Solutions, liquids and equilibrium data

These Web and Library sources have data on dissociation constants (pK, ionisation constants), solubility, equilibrium and other solution and liquid properties. See also other data sections of Chemistry resources.

Dissociation constants
(pK, ionisation constants)

Sources devoted to dissociation constants include:

Bordwell pKa table, University of Wisconsin

Dissociation constants of organic bases in aqueous solution. D.D. Perrin. Butterworths, 1965. Main collection 547 P456 and Waite Books 541.13 P45

Dissociation constants of organic acids in aqueous solution. G.Kortum, W.Vogel and K.Andrussow. Butterworth, 1961. (Pure and applied chemistry vol 1(2-3). Reference collection 540.5 P98 and Waite Books 541.13 K85

Ionisation constants of inorganic acids and bases in aqueous solution. D.D. Perrin. 2nd ed. Pergamon Press, 1982. Reference collection 541.3722 P458I

Acid-base dissociation constants in dipolar aprotic solvents. Compiled by Kosuke Izutsu. Blackwell Scientific Publications, 1990. Chemical data series ; no. 35. Reference collection 541.34 I99a

Dissociation constants for organic and inorganic compounds are also in:

CRC handbook of chemistry and physics. 76th ed. 1995-96. Reference collection 540.212 C11.76
Lange's handbook of chemistry. 14th ed. 1992. Reference collection 540.202 L274l.14 section 8
Macmillan's chemical and physical data. 1992. Reference collection 540.212 J27m
Book of data. 1985. Reference collection 502.12 E47b
Landolt-Bornstein Zahlenwerte und Funktionen ... 6th ed, Band II teil 7, p. 839-937. Reference collection 541.9 L25.6 2.7
International critical tables of numerical data: physics, chemistry and technology. Vol. VI, p. 259-304. Reference collection 530.8 N277
Electrochemical data. 1975. Main collection 541.37 D633e.E
The determination of ionization constants : a laboratory manual. 2nd ed, 1971. Chapter 8. Main collection 541 A335d.
Toxnet for substances of toxicological interest
Gmelin Handbuch der anorganischen Chemie. 8th ed. 1929-1994 Main collection 546 G569 - for inorganic compounds

Dissociation constants for organic compounds are also in:

CRC handbook of tables for organic compound identification. 3rd ed. 1976. Main collection 547.00212 C517c
Encyclopedia of reagents for organic synthesis. 1995. Reference collection 547.203 P219e
Dictionary of organic compounds
Comprehensive heterocyclic chemistry. Main collection 547.59 C737 - see its Physical data index in volume 8 under the substance name which sometimes leads to pKa values
CRC handbook of basic tables for chemical analysis. Reference collection 543.00212 B898c - for common buffers: page 469
Data for biochemical research. 3rd ed.1986. Reference collection 574.1920212 D232 - especially biochemical compounds
Beilstein Handbuch der organischen Chemie. 4th ed. 1918-1950s, incomplete. Main collection 547 B42.4
Determination of organic structures by physical methods. Ed. E.A. Braude. Academic Press, 1955. Main collection 547 B82. Chapter 14, p. 567 - includes discussion and tables of dissociation constants.

IUPAC-NIST Solubility Database

Contains a large set of solubility data for inorganic and organic solutes and solvents, some critically evaluated.

Handbook of aqueous solubility data. S.H. Yalkowsky. CRC Press, 2003.

Reference collection 547.1342 Y191h
Solubility of 4,000 organic nonelectrolytes and un-ionized weak electrolytes in water. Includes pharmaceuticals, pollutants, nutrients, herbicides, pesticdes, agricultural and industrial compounds.

Solubilities: inorganic and metal organic compounds, a compilation of solubility data from the periodical literature. 4th ed. 1958-65. 2 vols.

Reference collection 541 L756
Solubility of inorganic and organometallic compounds in water, acids, bases, salts, aqueous solvents, anhydrous solvents and fused salts.

Solubilities of inorganic and organic compounds. Ed. H Stephen. Pergamon Press, 1963. 4 vols.

Reference collection 541 V985
Includes the solubility of elements, inorganic, organometallic, organic compounds in water and other solvents in binary, ternary and multi-component systems.

Journal of physical and chemical reference data

Reference collection 530.805 J86 and online, 2000-
Look under solubility in the cumulative Property index in volumes 10 and 20 and in the last issue of the most recent complete volume. From vol 66, 1998, the IUPAC-NIST Solubility data series is published in JPCRD.

Also containing some solubility data are:

Chemistry Webbook, National Institute of Standards and Technology
ChemFinder
Toxnet for substances of toxicological interest
Dictionary of organic compounds
CRC handbook of chemistry and physics. 84th ed. 2003-2004. Reference collection 540.212 C11 - organic and inorganic compounds
Lange's handbook of chemistry. 14th ed. 1992. Reference collection 540.202 L274l.14 - organic and inorganic compounds in various solvents
Macmillan's chemical and physical data. 1992. Reference collection 540.212 J27m - inorganic, organic, organometallic, biochemical compounds
International critical tables of numerical data, physics, chemistry and technology. E.W. Washburn. 1926-33. Reference collection 530.8 N277

Tables of physical and chemical constants. G.W.C. Kaye and T.H. Laby. 16th ed. 1995. Reference collection 530.8 K23t.16 - inorganic compounds in water
Book of data. Ed. H. Ellis. Reference collection 502.12 E47b - inorganic compounds in water
Synthetic methods of organometallic and inorganic chemistry. Ed. W.A. Hermann. 1995-1997. 8 vols. Main Collection 547.051 H568s
Gmelin Handbuch der anorganischen Chemie. 8th ed. 1929-1994 Main collection 546 G569 - for inorganic compounds
Electrochemical data. B.E. Conway. 1952. Main collection 541 C76

Thermodynamic and physical property data: comprehensive thermodynamic and physical property data for hydrocarbons and organic chemicals. C L. Yaws. c1992. Reference collection 547.136 Y35t - 700 hydrocarbons and organic compounds of oxygen, nitrogen, halogen and sulfur.
Handbook of environmental data on organic chemicals. Karel Verschueren. 3rd ed. 1996. Reference collection 547 V562h.3
Data for biochemical research. 3rd ed.1986. Reference collection 574.1920212 D232 - especially biochemical compounds
Beilstein Handbuch der organischen Chemie. 4th ed. 1918-1950s, incomplete. Main collection 547 B42.4
Agrochemicals handbook. 3rd ed.1991- Reference collection 668.65 H332a.3

Critical stability constants. A.E. Martell. Plenum Press, 1974-77. 4 vols.

Main collection 541.392 M376c

Contains critically evaluated metal complex equilibrium constants and corresponding enthalpy and entropy values. Data are arranged by ligand in 4 volumes: 1. Amino acids. 2. Amines. 3. Other organic ligands. 4. Inorganic complexes. Has a ligand name and formula index in each volume.

Stability constants of metal-ion complexes. L.G. Sillen. 2nd ed. Chemical Society, 1964-68. Supplement, 1971.

Main collection 541.39 C517s.2
Contains equilibrium constants from the literature to 1968. Data are not critically evaluated. Has indexes by ligand name and metal.

The physico-chemical constants of binary systems in concentrated solutions. 1959-60. 4 vols.

Main collection 547 T58

Azeotropic data-III. 1973.

Reference collection 547.136 A993 3